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Antigua América by Los Jaivas
Great guitar solo played by Eduardo 'Gato' Alquinta
Solo starting at 4:40
Lines in the Sand is another great Petrucci solo which helps prove he has soul.

Recent discovery and one of my new favorites:
The Sails of Charon by Scorpions
Solo by Uli Jon Roth
The guitar solo goes right after the intro
Slash solo, Only women bleed (Alice Cooper cover during a concert in Tokyo)
Free bird! It starts 4:55